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Unit Information
Atomic history and radioactivity corresponds to chapters 8 and 17 in the text Foundations of College Chemistry by Hein and Arena..  Chapter 8 is an introduction to chemical reactions and equations.  Chapter 17 focuses solely on the redox process.
Assignments:
Text Problems Writing Reaction Equations - Solutions
Balancing Equations - Solutions - Which ones are redox? Writing More Reaction Equations - Solutions
Predicting Products - Solutions  
States of Matter
Predicting states of matter from a sentence equation can be difficult, but the clues given below are meant to help you out.
  1. The following are gases at room temperature:
    • Elements hydrogen, nitrogen, oxygen, fluorine, chlorine
    • ammonia
    • carbon monoxide and carbon dioxide
    • nitrogen monoxide and nitrogen dioxide
    • sulfur dioxide and sulfur trioxide
    • hydrogen-compounds (e.g. hydrogen chloride and hydrogen cyanide)
  2. Acids are aqueous.  Any phrases that refer to being dissolved or in solution means the compound is aqueous.
  3. Liquids − bromine, mercury, and water
  4. All other elements are solids.  When in doubt, so are most other compounds, particularly ionic compounds.
Types of Reactions

1.  Combustion – The reaction of a hydrocarbon with oxygen in the presence of heat to produce carbon dioxide and water vapor. 

  • If the supply of oxygen is limited (incomplete combustion), carbon monoxide is produced instead of carbon dioxide.
  • If the supply of oxygen is sufficient, or in excess (complete combustion), carbon dioxide is produced as stated above.
  • When nothing else is indicated, go with carbon dioxide.

 2.   Synthesis (Direct Combination) – The combination of two or more elements/compounds to produce one compound.

 3.  Decomposition – The breaking down of a compound (frequently with heat or electricity) into its elements or other smaller compounds.

  • Chlorates – decompose into metal chlorides and oxygen.
  • Carbonates – decompose into metal oxides and carbon dioxide

4.  Single Displacement/Replacement – The more “active” metal or halogen takes the place of another metal or halogen in a compound.  The replaced metal or halogen is left in its free state.

  • Always consult an activity series to make sure the reaction works.
  • If the reaction does not work, write “no reaction.”

 5.  Double Displacement/Replacement or Metathesis – The ions of two aqueous compounds switch partners to produce at least one precipitate.

  • Always consult a solubility table to make sure the reaction works.
  • If the reaction does not work, write “no reaction.”

 6.  Oxidation/Reduction – A reaction where one element loses electrons (oxidized) from reactants to products, and another element gains electrons (reduced) from reactants to products.

  • Single displacement and combustion reactions are ALWAYS redox.
  • Reactions involving free elements as either reactants or products are redox. This will include many synthesis and decomposition reactions.
  • Double displacement reactions are NEVER redox.  The charges of the ions do not change when they switch
  • Look for polyatomic ions that have been broken down because they usually contain an element that has been oxidized or reduced.

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Last update: Thursday, June 16, 2011